Slater's rules

Slater's rules

Slater's Rules are a set of rules devised by John C. Slater that give an approximate estimate of effective nuclear charge on an electron (Z*).


where S is the screening constant.

The system involves the two following steps:

# Arrange sets according to principal quantum number, ignoring filling order and keeping ns and np together
#: i.e [1s] [2s,2p] [3s,3p] [3d] [4s,4p] [4d] [4f]
# Using the table, calculate the contributions to S (the screening constant) for electrons in each set.

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