- Ionic liquid
An ionic liquid is a liquid that contains essentially only ions. Some ionic liquids, such as
ethylammonium nitrateare in a dynamic equilibrium where at any time more than 99.99% of the liquid is made up of ionic rather than molecular species. In the broad sense, the term includes all molten salts, for instance, sodium chlorideat temperatures higher than 800 °C. Today, however, the term "ionic liquid" is commonly used for salts whose melting pointis relatively low (below 100 °C). In particular, the salts that are liquid at room temperature are called room-temperature ionic liquids, or RTILs. There also exist mixtures of substances which have low melting points, called Deep eutectic solvent, or DES, that have many similarities with ionic liquids.
The date of discovery, as well as discoverer, of the "first" ionic liquid is disputed. Ethanolammonium nitrate (m.p. 52-55 °C) was reported in 1888 by Gabriel. [cite journal | title = Ueber einige Abkömmlinge des Propylamins | journal =
Ber.| volume = 21 | issue = 2 | year = 1888 | pages = 2669–2679 | author = S. Gabriel, J. Weiner | doi = 10.1002/cber.18880210288] However, one of the earlier known truly room temperature ionic liquids was [EtNH3] + [NO3] - (m.p. 12 °C), the synthesis of which was published in 1914. [P. Walden, Bull. Acad. Sci. St. Petersburg 1914, 405-422] Much later, series of ionic liquids based on mixtures of 1,3-dialkylimidazolium or 1-alkylpyridinium halides and trihalogenoaluminates, initially developed for use as electrolytes, were to follow. [cite journal | title = Electrochemical scrutiny of organometallic iron complexes and hexamethylbenzene in a room temperature molten salt | author = H. L. Chum, V. R. Koch, L. L. Miller, R. A. Osteryoung | journal = J. Am. Chem. Soc.| year = 1975 | volume = 97 | pages = 3264 | doi = 10.1021/ja00844a081] [cite journal | title = Dialkylimidazolium chloroaluminate melts: a new class of room-temperature ionic liquids for electrochemistry, spectroscopy and synthesis | author = J. S. Wilkes, J. A. Levisky, R. A. Wilson, C. L. Hussey | journal = Inorg. Chem.| year = 1982 | volume = 21 | pages = 1263–1264 | doi = 10.1021/ic00133a078] An important property of the imidazolium halogenoaluminate salts was that they were tuneable – viscosity, melting pointand the acidityof the melt could be adjusted by changing the alkylsubstituents and the ratio of imidazoliumor pyridiniumhalide to halogenoaluminate. [cite journal | title = Potentiometric investigation of dialuminium heptachloride formation in aluminum chloride-1-butylpyridinium chloride mixtures | author = R. J. Gale, R. A. Osteryoung | journal = Inorganic Chemistry | year = 1979 | volume = 18 | pages = 1603 | doi = 10.1021/ic50196a044]
A major drawback was their moisture sensitivity and, though to a somewhat lesser extent, their acidity/basicity, the latter which can sometimes be used to an advantage. In 1992, Wilkes and Zawarotko reported the preparation of ionic liquids with alternative, 'neutral',
weakly coordinating anions such as hexafluorophosphate( [PF6] -) and tetrafluoroborate( [BF4] )-, allowing a much wider range of applications for ionic liquids. [J. S. Wilkes, M. J. Zaworotko Chemical Communications 1992, 965-967] It was not until recently that a class of new, air- and moisture stable, neutral ionic liquids, was available that the field attracted significant interest from the wider scientific community.
More recently, people have been moving away from [PF6] - and [BF4] - since they are highly toxic, and towards new anions such as
bistriflimide[(CF3SO2)2N] - or even away from halogenated compounds completely. Moves towards less toxic cations have also been growing, with compounds like ammonium salts (such as choline) being just as flexible a scaffold as imidazole.
Ionic liquids are electrically conductive and have extremely low
vapor pressure. (Their noticeable odours are likely due to impurities.) Their other properties are diverse. Many have low combustibility, excellent thermal stability, a wide liquid range, and favorable solvating properties for diverse compounds. Many classes of chemical reactions, such as Diels-Alder reactions and Friedel-Crafts reactions, can be performed using ionic liquids as solvents. Recent work has shown that ionic liquids can serve as solvents for biocatalysis [cite journal | title = Cofactor-dependent enzyme catalysis in functionalized ionic solvents | author = Adam J. Walker and Neil C. Bruce | journal = Chemical Communications| year = 2004 | volume = 2004 | pages = 2570 | doi = 10.1039/b410467f] . The miscibility of ionic liquids with water or organic solventsvaries with sidechain lengths on the cation and with choice of anion. They can be functionalized to act as acids, bases or ligands, and have been used as precursor salts in the preparation of stable carbenes. Because of their distinctive properties, ionic liquids are attracting increasing attention in many fields, including organic chemistry, electrochemistry, catalysis, physical chemistry, and engineering; see for instance magnetic ionic liquid.
Despite their extremely low vapor pressures, some ionic liquids can be
distilled under vacuum conditions at temperatures near 300 °C. [cite journal | title = The distillation and volatility of ionic liquids | author = Martyn J. Earle, José M.S.S. Esperança, Manuela A. Gilea, José N. Canongia Lopes, Luís P.N. Rebelo, Joseph W. Magee, Kenneth R. Seddon and Jason A. Widegren | journal = Nature | year = 2006 volume = 439 | pages = 831 | doi = 10.1038/nature04451 | volume = 439] Some ionic liquids (such as 1-butyl-3-methylimidazolium nitrate) generate flammable gases on thermal decomposition. Thermal stability and melting pointdepend on the components of the liquid. Thermal stability of various RTILs are available. The thermal stability of a task-specific ionic liquid, protonated betaine bis(trifluoromethanesulfonyl)imide is of about 534 K and N-Butyl-N-Methyl pyrrolidinium bis(trifluoromethanesulfonyl)imide was thermally stable up to 640 K [ Ch.Jagadeeswara Rao, R. Venkata krishnan, K. A. Venkatesan, K. Nagarajan, 332 - 334, Feb. 4-6, Sixteenth national symposium on thermal analysis(Thermans 2008)]
The solubility of different species in imidazolium ionic liquids depends mainly on polarity and hydrogen bonding ability. Simple
aliphaticcompounds are generally only sparingly solublein ionic liquids, whereas olefins show somewhat greater solubility, and aldehydes can be completely miscible. This can be exploited in biphasic catalysis, such as hydrogenationand hydrocarbonylation processes, allowing for relatively easy separation of products and/or unreacted substrate(s). Gas solubility follows the same trend, with carbon dioxidegas showing exceptional solubility in many ionic liquids, carbon monoxidebeing less soluble in ionic liquids than in many popular organic solvents, and hydrogenbeing only slightly soluble (similar to the solubility in water) and probably varying relatively little between the more popular ionic liquids. (Different analytical techniques have yielded somewhat different absolute solubility values.)
Room temperature ionic liquids
Room temperature ionic liquids consist of bulky and asymmetric organic
cationssuch as 1-alkyl-3-methylimidazolium, 1-alkylpyridinium, N-methyl-N-alkylpyrrolidinium and ammoniumions. A wide range of anions are employed, from simple halides, which generally inflect high melting points, to inorganic anions such as tetrafluoroborateand hexafluorophosphateand to large organic anions like bistriflimide, triflateor tosylate. There are also many interesting examples of uses of ionic liquids with simple non-halogenated organic anions such as formate, alkylsulfate, alkylphosphate or glycolate. As an example, the melting point of 1-butyl-3-methylimidazolium tetrafluoroborateor [bmim] [BF4] with an imidazoleskeleton is about -80 °C, and it is a colorless liquid with high viscosityat room temperature.
It has been pointed out that in many synthetic processes using transition metal catalyst, metal nanoparticles play an important role as the actual catalyst or as a catalyst reservoir. It also been shown that ionic liquids (ILs) are an appealing medium for the formation and stabilization of catalytically active transition metal nanoparticles. More importantly, ILs can be made that incorporate co-ordinating groups, [cite journal | title = Applications of Functionalized Ionic Liquids | author = X. Li, D. Zhao, Z. Fei, L. Wang | journal =
Science in China: B | year = 2006 | volume = 35 | pages = 181 | doi = 10.1007/s11426-006-2020-y] , for example, with nitrilegroups on either the cationor anion(CN-IL). In various C-C coupling reactions catalyzed by palladium catalyst, it has been found the palladium nanoparticles are better stabilized in CN-IL compared to non-functionalized ionic liquids; thus enhanced catalytic activity and recyclability are realized. [cite journal | author = Zhao, D.; Fei, Z.; Geldbach, T. J.; Scopelliti, R.; Dyson, P. J. | journal = J. Am. Chem. Soc.| year = 2004 | volume = 126 | pages = 15876 | title = Nitrile-Functionalized Pyridinium Ionic Liquids: Synthesis, Characterization, and Their Application in Carbon-Carbon Coupling Reactions | doi = 10.1021/ja0463482]
Low temperature ionic liquids
Low temperature ionic liquids (below 130
kelvins) have been proposed as the fluid base for an extremely large diameter spinning liquid mirror telescope to be based on the earth's moon. [cite journal | author = E. F. Borra, O. Seddiki, R. Angel, D. Eisenstein, P. Hickson, K. R. Seddon and S. P. Worden | title = Deposition of metal films on an ionic liquid as a basis for a lunar telescope | year = 2007 | journal = Nature | volume = 447 | issue = 7147 | pages = 979–981 | doi = 10.1038/nature05909] Low temperature is advantageous in imaging long wave infrared light which is the form of light (extremely red-shifted) that arrives from the most distant parts of the visible universe. Such a liquid base would be covered by a thin metallic film that forms the reflective surface. A low volatility is important for use in the vacuum conditions present on the moon.
Ionic liquids have been used in
food science. [bmim] Cl for instance is able to completely dissolve freeze dried bananapulp and the solution with an additional 15% DMSO lends itself to Carbon-13 NMRanalysis. In this way the entire banana compositional makeup of starch, sucrose, glucose, and fructosecan be monitored as a function of banana ripening. [Fort, D.A, Swatloski, R.P., Moyna, P., Rogers, R.D., Moyna, G. "Chem. Commun." 2006, 714]
Nowadays ionic liquids find a number of industrial applications which vary greatly in character. A few of their industrial applications are briefly described below; more detailed information can be found in a recent review article. [Plechkova, N.V., Seddon, K.R., 2008, Chem. Soc. Rev., 123]
The first major industrial application of ILs was the BASIL ("B"iphasic "A"cid "S"cavenging utilizing "I"onic "L"iquids) process by
BASF, in which a 1-alkylimidazole was used to scavenge the acid from an existing process. This then results in the formation of an IL which can easily be removed from the reaction mixture. [cite press release | publisher = BASF| url = http://www.basf.com/corporate/051004_ionic.htm | title = BASF to present BASIL™ ionic liquid process at technology transfer forum | date = 2004-05-10] But the easier removal of an unwanted side-product (as an IL rather than as a solid salt) is not the only advantage of the IL based process. By using an IL it was possible to increase the space/time yield of the reaction by a factor of 80,000. It should, however, be kept in mind that improvements of such scale are rare.Fact|date=April 2008
Occurring at a volume of some 700 billion tons,
celluloseis the earth’s most widespread natural organic chemical and, thus, highly important as a bio-renewable resource. But even out of the 40 billion tons nature renews every year, only approx. 0.2 billion tons are used as feedstock for further processing. A more intensive exploitation of cellulose as a bio-renewable feedstock has to date been prevented by the lack of a suitable solvent that can be used in chemical processes. Robin Rogers and co-workers at the University of Alabama have found that by means of ionic liquids, however, real solutions of cellulose can now be produced for the first time at technically useful concentrations [cite journal | title = Dissolution of Cellulose with Ionic Liquids | author = Richard P. Swatloski, Scott K. Spear, John D. Holbrey, and Robin D. Rogers | journal = Journal of the American Chemical Society| year = 2002 | volume = 124/18 | pages = 4974–4975 | doi = 10.1021/ja025790m] . This new technology therefore opens up great potential for cellulose processing.
For example, making cellulosic fibers from so-called dissolving pulp currently involves the use, and subsequent disposal, of great volumes of various chemical auxiliaries, esp. carbon disulfide (CS2). Major volumes of waste water are also produced for process reasons and need to be disposed of. These processes can be greatly simplified by the use of ionic liquids, which serve as solvents and are nearly entirely recycled. The “Institut für Textilchemie und Chemiefasern” (ITCF) in Denkendorf and BASF are jointly investigating the properties of fibers spun from an ionic liquid solution of cellulose in a pilot plant setup. [ Frank Hermanutz, Frank Gähr, Klemens Massonne, Eric Uerdingen, oral presentation at the 45th Chemiefasertagung, Dornbirn, Austria, September 20th – 22nd, 2006] The dissolution of cellulose based materials like tissue paper waste, that generated at chemical industries and at research laboratories, in room temperature ionic liquid, 1-butyl-3-methylimidazolium chloride, bmimCl, was studied and the recovery of valuable compounds by electrodeposition was studied from this cellulose matrix. [cite journal | journal =
Electrochimica Acta| volume = 53 | issue = 4 | year = 2007 | pages = 1911–1919 | title = Treatment of tissue paper containing radioactive waste and electrochemical recovery of valuables using ionic liquids | author = Ch. Jagadeeswara Raoa, K.A. Venkatesana, K. Nagarajana, T.G. Srinivasan and P.R. Vasudeva Rao | doi = 10.1016/j.electacta.2007.08.043] .
Eastman chemical’s DHF plant
Eastman operated an ionic liquid-based plant for the synthesis of
2,5-dihydrofuranfrom 1996 to 2004. However, the plant is now defunct because demand for the product has ceased.Fact|date=April 2008
Dimersol - Difasol
The dimersol process is a traditional way to dimerise short chain alkenes into branched alkenes of higher molecular weight. Nobel laureate Yves Chauvin and Hélène Olivier-Bourbigou at IFP (France) have developed an ionic liquid-based add-on to this process called the Difasol process. However, while may be licensed it has as yet not been put into commercial practice.
Petrochina have announced the implementation of an ionic liquid-based process called Ionikylation. This process, the alkylation of C4 olefins with iso-butane, is retrofitted into a 65,000 tonne per year alkylation plant, making it the biggest industrial application of ILs to date.
Degussa paint additives
Ionic liquids can enhance the finish, appearance and drying properties of paints. Degussa are marketing such ILs under the name of TEGO Dispers. These products are also added to the Pliolite paint range.
Air products - ILs as a transport medium for reactive gases
Air products make use of ILs as a medium to transport reactive gases in. Reactive gases such as trifluoroborane, phosphine or arsine, BF3, PH3 or AsH3, respectively, are stored in suitable ILs at sub-ambient pressure. This is a significant improvement over pressurised cylinders. The gases are easily withdrawn from the containers by applying a vacuum.
Linde's IL 'piston'
Whereas Air Product’s Gasguard system relies on the solubility of some gases in ILs, Linde are exploiting other gases’ insolubility in ILs. As mentioned above, the solubility of
hydrogenin ILs is very low. Linde now make use of this insolubility by using a body of ionic liquid to compress hydrogen up to 450 bar [ [http://www.zemships.eu/en/DateienDownload/Zemships_Newsletter_Juli_08_english.pdf Zemships - Ionic liquid compression] ] in filling stations; and in so doing they reduced the number of moving parts from about 500 in a conventional piston pump engine down to 8.
IOLITEC's dispersions of nano-materials
It is well known that ILs can be used for the synthesis of nano-scaled materials. IOLITEC has developed a couple of methods for the dispersion of different combinations of solvents and nano-materials, using the unusual physical properties of ionic liquids. The dispersion is useful, since it enables a safer use of nano-scaled materials in typical applications.
RTILs are extensively explored for various innovative applications in nuclear industry. It includes application of ionic liquid as extractant/diluent in solvent extraction systems, as alternate electrolyte media for the high temperature pyrochemical processing, etc. Fundamental studies on the extraction methods for electrodeposition of fission products like uranium, palladium etc., from spent nuclear fuel using RTILs as extractants are reported. Reports on employing using Ionic liquids as non-aqueous electrolyte media for the recovery of uranium [Electrochemical behavior of uranium(VI) in 1-butyl-3-methylimidazolium chloride and thermal characterization of uranium oxide deposit, "Electrochimica Acta", Volume 52, Issue 9, 15 February 2007, Pages 3006-3012, P. Giridhar, K.A. Venkatesan, T.G. Srinivasan and P.R. Vasudeva Rao] and useful fission products like palladium [Electrochemical behavior of fission palladium in 1-butyl-3-methylimidazolium chloride "Electrochimica Acta", Volume 52, Issue 24, 1 August 2007, Pages 7121-7127, M. Jayakumar, K.A. Venkatesan and T.G. Srinivasan, http://dx.doi.org/10.1016/j.electacta.2007.05.049 ] and rhodium [Electrochemical behavior of rhodium(III) in 1-butyl-3-methylimidazolium chloride ionic liquid, "Electrochimica Acta", Volume 53, Issue 6, 15 February 2008, Pages 2794-2801 M. Jayakumar, K.A. Venkatesan and T.G. Srinivasan, http://dx.doi.org/10.1016/j.electacta.2007.10.056 ] from spent nuclear fuel are also available.Studies on the electrochemical behavior of uranium(VI) in ionic liquid, 1-butyl-3-methylimidazolium chloride and also the recovery of valuable fission products from tissue paper waste was studied in room temperature ionic liquids. [cite journal | journal =
Electrochimica Acta| volume = 53 | issue = 4 | year = 2007 | pages = 1911–1919 | title = Treatment of tissue paper containing radioactive waste and electrochemical recovery of valuables using ionic liquids | author = Ch. Jagadeeswara Raoa, K.A. Venkatesana, K. Nagarajana, T.G. Srinivasan and P.R. Vasudeva Rao | doi = 10.1016/j.electacta.2007.08.043] . The dissolution properties of uranium oxides, UO3, UO2, and U3O8 and their individual separation was studied using a task-specific ionic liquid, namely protonated betaine bis(trifluoromethanesulfonyl) imide, [Hbet] [NTf2] . [ Dissolution of uranium oxides and electrochemical behavior of U(VI) in task specific ionic liquid by Ch. Jagadeeswara Raoa, K.A. Venkatesana, K. Nagarajana, T.G. Srinivasan,Radiochimica acta, volume 96,issue 7 pages 403 - 409, 2008 doi: 10.1524/ract.2008.1508] .
Ionic liquids have several properties that make them viable options for hydrogen storage systems. For instance, the vapor pressure of ionic liquids is very low and is negligible in most situations. These liquid are also stable at high temperatures. In addition, ionic liquids are able to great solvents for a wide variety of compounds and gases, they also have have weakly coordinating anions and cations which are able to stabilize polar transition states. Finally, the liquids are able to be reused with minimal loss of activity. In their research Karkamkar et al used 1-butyl-3-methylimidazolium chloride (bmimCl) in the dehydrogenation of ammonia borane. Immediately upon heatings the sample, hydrogen evolution took place with a final value of hydrogen evolution as high as 5.4 wt% H2 [cite journal | journal = Material Matters | url = http://www.sigmaaldrich.com/aldrich/brochure/al_material_matters_v2n2.pdf | volume = 2 | issue = 2 | year = 2007 | pages = 6–9 | title = Recent Developments on Hydrogen Release from Ammonia Borane| author = A. Karkamkar, C. Aardahl, T. Autrey] .
Due to their non-volatility, effectively eliminating a major pathway for environmental release and contamination, ionic liquids have been considered as having a low impact on the environment and human health, and thus recognized as solvents for
green chemistry. However, this is distinct from toxicity, and it remains to be seen how 'environmentally-friendly' ILs will be regarded once widely used by industry. Research into IL aquatic toxicity has shown them to be as toxic or more so than many current solvents already in use [cite journal | title = Acute toxicity of ionic liquids to the zebrafish (Danio rerio) | author = C Pretti, C Chiappe, D Pieraccini, M Gregori, F Abramo, G Monni and L Intorre | journal = Green Chem.| year = 2006 | volume = 8 | pages = 238–240 | doi = 10.1039/b511554j] . A review paper on this aspect has been published in 2007. [cite journal | author = D. Zhao, Y. Liao and Z. Zhang | title = Toxicity of Ionic Liquids | year = 2007 | journal = CLEAN - Soil, Air, Water| volume = 35 | issue = 1 | pages = 42–48 | doi = 10.1002/clen.200600015] Available research also shows that mortality isn't necessarily the most important metric for measuring their impacts in aquatic environments, as sub-lethal concentrations have been shown to change organisms' life histories in meaningful ways. According to these researchers balancing between zero VOC emissions, and avoiding spills into waterways (via waste ponds/streams, etc.) should become a top priority. However, with the enormous diversity of substituents available to make useful ILs, it should be possible to design them with useful physical properties and less toxic chemical properties.
With regard to the safe disposal of ionic liquids, a 2007 paper has reported the use of
ultrasoundto degrade solutions of imidazolium-based ionic liquids with hydrogen peroxideand acetic acidto relatively innocuous compounds. [cite journal| title = Ultrasonic chemical oxidative degradations of 1,3-dialkylimidazolium ionic liquids and their mechanistic elucidations | author = Xuehui Li, Jinggan Zhao, Qianhe Li, Lefu Wang and Shik Chi Tsang | journal = Dalton Trans.| date = 2007 | doi = 10.1039/b618384k| pages = 1875]
Despite their low
vapor pressuremany ionic liquids have also found to be combustible and therefore require careful handling [cite journal | title = Combustible ionic liquids by design: is laboratory safety another ionic liquid myth? | author = Marcin Smiglak, W. Mathew Reichert, John D. Holbrey, John S. Wilkes, Luyi Sun, Joseph S. Thrasher, Kostyantyn Kirichenko, Shailendra Singh, Alan R. Katritzkyand Robin D. Rogers | journal = Chemical Communications| year = 2006 | volume = 2006 | pages = 2554–2556 | doi = 10.1039/b602086k] . Brief exposure (5 to 7 seconds) to a flame torch will ignite these IL's and some of them are even completely consumed by combustion.
1-Butyl-3-methylimidazolium hexafluorophosphate(BMIM-PF6) for an often encountered ionic liquid.
Aza-Baylis-Hillman reactionfor the use of a chiral ionic liquid in asymmetric synthesis.
Deep eutectic solvent
1st international Ionic Liquids web portal[http://www.aails.com all around ionic liquids]
*cite journal | title = Air and water stable ionic liquids in physical chemistry | author = F. Endres, S. Zein El Abedin | journal =
Phys. Chem. Chem. Phys.| volume = 8 | year = 2006 | pages = 2101 | doi = 10.1039/b600519p
*cite journal | author = S. Fujita, H. Kanamaru, H. Senboku and M. Arai | title = Preparation of Cyclic Urethanes from Amino Alcohols and Carbon Dioxide Using Ionic Liquid Catalysts with Alkali Metal Promoters | journal =
Int. J. Mol. Sci.| year = 2006 | volume = 2006 | issue = 7 | pages = 438–450 | url = http://www.mdpi.org/ijms/papers/i7100438.pdf | format = open access
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