Outgassing (sometimes called offgassing, particularly when in reference to indoor air quality) is the release of a gas that was dissolved, trapped, frozen or absorbed in some material. As an example, research has shown how the concentration of carbon dioxide in the Earth's atmosphere has sometimes been linked to ocean outgassing.  It can include sublimation and evaporation which are phase transitions of a substance into a gas, as well as desorption, seepage from cracks or internal volumes and gaseous products of slow chemical reactions. Boiling is generally thought of as a separate phenomenon from outgassing because it consists of a phase transition of a liquid into a vapor made of the same substance.
Outgassing in a vacuum
Outgassing is a challenge to creating and maintaining clean high-vacuum environments. NASA maintains a list of low-outgassing materials to be used for spacecraft, as outgassing products can condense onto optical elements, thermal radiators, or solar cells and obscure them. Materials not normally considered absorbent can release enough light-weight molecules to interfere with industrial or scientific vacuum processes. Moisture, sealants, lubricants, and adhesives are the most common sources, but even metals and glasses can release gases from cracks or impurities. The rate of outgassing increases at higher temperatures because the vapour pressure and rate of chemical reaction increases. For most solid materials, the method of manufacture and preparation can reduce the level of outgassing significantly. Cleaning surfaces or baking individual components or the entire assembly before use can drive off volatiles.
NASA's Stardust spaceprobe suffered reduced image quality due to an unknown contaminant that had condensed on the CCD sensor of the navigation camera. A similar problem affected the Cassini-Huygens spaceprobe's Narrow Angle Camera, but was corrected by repeatedly heating the system to 4 degrees Celsius. A comprehensive characterisation of outgassing effects using mass spectrometers could be obtained for ESA's Rosetta spacecraft.
Outgassing from rock
Outgassing is the source of many tenuous atmospheres of terrestrial planets or moons. Many materials are volatile relative to the extreme vacuum of space, such as around the Earth's Moon, and may evaporate or even boil at ambient temperature. Materials on the lunar surface have completely outgassed and been ripped away by solar winds long ago, but volatile materials may remain at depth. Once released, gases almost always are less dense than the surrounding rocks and sand and seep toward the surface. The lunar atmosphere probably originates from outgassing of warm material below the surface. At the Earth's tectonic divergent boundaries where new crust is being created, helium and carbon dioxide are some of the volatiles being outgassed from mantle magma.
Outgassing in a closed environment
Outgassing can be significant if it collects in a closed environment where air is stagnant or recirculated. This is, for example, the origin of new car smell. Even a nearly odourless material such as wood may build up a strong smell if kept in a closed box for months. There is some concern that softeners and solvents that are released from many industrial products, especially plastics, may be harmful to human health.. Some types of RTV sealants outgas the poison cyanide for weeks after application. These outgassing poisons are of great concern in the design of submarines and space stations.
Note: VOCs don't outgas; they create a significant vapor pressure not because they have absorbed gas, but because they break down (depolymerize) due to time, light, and heat.
- Outgassing Data for Selecting Spacecraft Materials Online (NASA database)
- Outgassing Data For Common Materials
- ESA Outgassing Data for Spacecraft Materials according to ECSS-Q-70-02
- ^ Strong, John (1938). Procedures in Experimental Physics. Bradley, IL: Lindsay Publications. , Chapter 3
- ^ http://www.gfdl.noaa.gov/bibliography/related_files/us9301.pdf
- ^ B. Schläppi, et al. (2010), Influence of spacecraft outgassing on the exploration of tenuous atmospheres with in situ mass spectrometry, J. Geophys. Res., 115, A12313, doi:10.1029/2010JA015734.
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