- Titanium powder
Titaniumpowder metallurgy (P/M) offers the possibility of creating net shape or near net shape parts without the material loss and cost associated with having to machine intricate components from wrought billet. Powders can be produced by the Blended Elemental Technique or by Pre-Alloying and then consolidated by Metal Injection Moulding, Hot Isostatically Pressing , Direct Powder Rolling or Laser Engineered Net Shaping.
Blended Elemental Technique (BE)
The traditional technique of titanium production is via the Kroll Process which involves chlorination of TiO2 ore in the presence of carbon and reacting the resulting TiCl4 with magnesium to produce titanium sponge. These processes take place at temperatures as high as 1040 °C. The sponge particle range in size from 45 to 180 µm, with particles ~150 µm termed ‘sponge fines’. These fines are irregularly shaped and porous with a sponge like morphology. The fines are then blended with alloy additions; cold compacted into a green compact at up to 415 MPa then vacuum sintered at 1260 °C to produce a 99.5% dense component. Hot Isostatically Pressing (HIP) can further increase the density of these parts and produce components more economically than cast or wrought parts, but the porosity present in the material degrades fatigue and fracture properties. The BE approach has been used to produce valves for the Toyota Altezza, golf club heads and softball bats. More recently, close to 100% dense Ti Grade 5 parts has been achieved using a hydrided powder along with 60:40 Al:V master alloy. The mechanical properties compare well with those exhibited by cast-and-wrought products. A cost estimate of less than $3.00 for a 0.320 gm automotive connection link has been made.
Pre-Alloyed Powder Production
Several techniques exist to produce pre-alloyed powder, such as Grade 5. In the Hydride-Dehydride process feedstock such as solid scrap, billet or machined turnings are processed to remove contaminants, hydrogenated to produce brittle material then ground under argon in a vibratory ball mill, typically at 400 °C for 4 hours at a pressure of 1psi for Ti Grade 5. The resulting particles are angular and measure between 50 and 300 µm. Cold compaction after dehydrogenation of the powder, followed by either vacuum hot pressing (in this case the dehydrogenation process can be bypassed as hydrogen is removed under vacuum) or HIP and a final vacuum anneal, produces powders with hydrogen below 125 ppm. The possible presence of contaminants makes these powders unsuitable for use in critical aircraft applications.
In the Plasma Rotating Electrode Process (PREP), the feedstock, such as Ti Grade 5, is in the form of a rotating bar which is arced with gas plasma. The molten metal is centrifugally flung off the bar, cools down and is collected. The powders produced are spherical; between 100 and 300 µm is size, with good packing and flow characteristics, making the powder ideal for high quality, near net shapes produced by HIP, such as aviation parts and porous coatings on hip prostheses.
In Gas Atomisation (TGA Process), titanium is vacuum induction skull melted in a water cooled copper crucible, the metal tapped and the molten metal stream atomized with a stream of high pressure inert gas. The tiny droplets are spherical and measure between 50 and 350 µm. The TGA process has been used to produce a wide variety of materials such as CP titanium, conventional alpha-beta and beta alloys.
Several metal consolidation techniques are used to produce the final product. Metal Injection Moulding (MIM) otherwise know as Powder Injection Moulding is a well-established and cost-effective method of fabricating small-to-moderate size metal components in large quantities. It is derived from the method plastic injection moulding, whereby mixing of a metal powder with a polymer binder forms the feedstock, which is then injected into a mould, after which the binder is removed via heat treatment under vacuum before final sintering. With titanium however, the binders used in MIM results in the introduction of carbon into the matrix due to insufficient binder removal prior to sintering and/or deleterious reactions between the decomposing binder, the debinding atmosphere, and the metal phase. This results in titanium parts with mechanical properties unsuited for critical aerospace applications, but suitable for parts where tensile and impact properties are less important. Recently, work has been carried out to reduce the binder to < 8% volume fraction, resulting in the complete removal of the binder from the moulded component during heat treatment. Work is still ongoing in this area.
Work is also progressing on the Direct Powder Rolling (DPR) process. BE powder is used to produce sheet and plate and composite multilayered sheet and plates. Sheets between 1.27 and 2.54 mm and 50 to 99+% dense of single layer C.P. Titanium, Ti Grade 5, TiAl (Ti-48Al-2Cr-2Nb) and composite Ti/Grade 5/Ti and Grade 5/TiAl/Grade 5 have been produced by DPR and sintering.
Laser Engineered Net Shaping(LENS) is an additive manufacturing technique for rapidly fabricating, enhancing and repairing metal components directly from CAD data. The processes use a high power solid state laser focused onto a metal substrate to create a ~1 mm diameter melt pool. Metal powder is then injected into the melt pool to increase the material volume and build up the component layer by layer. Experimental gas thrusters (build time 8 hours) and automotive brackets have been manufactured in Ti-Grade 5. Selective Laser Sintering (SLS) is similar, except that the laser selectively fuses powdered material by scanning on the surface of a powder bed. After each cross-section is scanned, the powder bed is lowered by one layer thickness, a new layer of material is applied on top, and the process is repeated until the part is completed. Hot Isostatic Pressinghas already been mentioned as is a technique whereby high temperature and pressure are used to consolidate powders to close to their maximum theoretical densities. Electric Current Assisted Sintering, also known as Spark Plasma Sintering (SPS), has been shown to utilize fast application of resistive heating and pressure to consolidate powders close to their maximum theoretical densities, without the undesired grain growth effect, thereby retaining close to original grain size and achieving improved mechanical properties in the final product.
Work is progressing on bypassing the conventional route of atomising wrought feedstock or sponge and the inherent cost associated with the traditional Kroll process. Several of these processes, such as the FFC, MER Corporation, OS, Ginatta and BHP Billiton processes rely on the electrolytic reduction of TiO2 (a cheap and abundant material) to form Ti metal. So far, no material from these processes has been sold commercially on the open market, and cost models have yet to be published, but they offer the possibility of inexpensive titanium powder in the near future.
* [http://www.titaniuminfogroup.co.uk Titanium Information Group]
* [http://www.powdermatrix.com PowderMatrix]
* [http://www.epma.com European Powder Metallugy Association]
* [http://www.pim-international.com Powder Injection Moulding International ] (ISSN 1753-1497) is a combined business-to-business magazine and scientific journal offering in-depth coverage of the metal, ceramic and carbide injection moulding industries.
Wikimedia Foundation. 2010.
Look at other dictionaries:
Titanium nitride — (titaniumnitrogen) (sometimes known as Tinite or TiNite) is an extremely hard ceramic material, often used as a coating on titanium alloy, steel, carbide, and aluminium components to improve the substrate s surface properties. Applied as a thin… … Wikipedia
Powder metallurgy — is the process of blending fine powdered materials, pressing them into a desired shape (compacting), and then heating the compressed material in a controlled atmosphere to bond the material (sintering). The powder metallurgy process generally… … Wikipedia
Titanium — Ti*ta ni*um, n. [NL., fr. L. Titani or Titanes, Gr. ?, the sons of the earth.] (Chem.) An elementary substance found combined in the minerals manaccanite, rutile, sphene, etc., and isolated as an infusible iron gray amorphous powder, having a… … The Collaborative International Dictionary of English
Titanium — This article is about the chemical element. For other uses, see Titanium (disambiguation). scandium ← titanium → vanadium … Wikipedia
Titanium dioxide — Chembox new Name = Titanium dioxide ImageFile = Titanium(IV) oxide.jpg ImageSize = 200px ImageName = Titanium(IV) oxide ImageFile1 = Rutile unit cell 3D balls.png ImageSize1 = 200px ImageName1 = The unit cell of rutile IUPACName = Titanium… … Wikipedia
Titanium(II) hydride — Chembox new Name = Titanium(II) hydride ImageFile = Titanium(II) hydride.jpg ImageName = Titanium(II) hydride OtherNames = titanium dihydride Section1 = Chembox Identifiers CASNo = 7704 98 5 Section2 = Chembox Properties Formula = TiH2 MolarMass … Wikipedia
Titanium boride — Chembox new ImageFile = ImageSize = IUPACName = OtherNames = Section1 = Chembox Identifiers CASNo = 12045 63 5 PubChem = SMILES = Section2 = Chembox Properties Formula = TiB2 MolarMass = 69.5 g/mol Appearance = metallic grey Density = MeltingPt … Wikipedia
titanium — /tuy tay nee euhm/, n. Chem. a dark gray or silvery, lustrous, very hard, light, corrosion resistant, metallic element, occurring combined in various minerals: used in metallurgy to remove oxygen and nitrogen from steel and to toughen it. Symbol … Universalium
Titanium(III) phosphide — Chembox new Name = Titanium(III) phosphide ImageFile = ImageSize = ImageName = OtherNames = titanium monophosphide Section1 = Chembox Identifiers CASNo = 12037 65 9 Section2 = Chembox Properties Formula = TiP MolarMass = 78.841 g/mol Appearance … Wikipedia
Titanium(III) oxide — Chembox new ImageName = IUPACName = titanium(III) oxide OtherNames = titanium sesquioxide Section1 = Chembox Identifiers CASNo = 1344 54 3 Section2 = Chembox Properties Formula = Ti2O3 MolarMass = 143.76 g/mol Appearance = violet black, odorless… … Wikipedia