Bromotrifluoromethane Identifiers CAS number PubChem ChemSpider EC number UN number 1009 RTECS number PA5425000 Jmol-3D images Image 1 Properties Molecular formula CBrF3 Molar mass 148.91 g mol−1 Appearance Colorless gas Density 1.538 g/cm3 (−58 °C) Melting point
Solubility in water 0.03 g/l (20 °C) log P 1.86 Vapor pressure 1434 kPa (20 °C) Hazards EU Index Not listed Flash point Non-flammable (what is: /?)
Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)
Table of physical properties
Property Value Critical temperature (Tc) 66.9 °C (340.08 K) Critical pressure (pc) 3.956 MPa (39.56 bar) Critical density (ρc) 5.13 mol.l−1 Ozone depletion potential (ODP) 10 (CCl3F = 1) Global warming potential (GWP) 6900 (CO2 = 1)
It was introduced as an effective gaseous fire suppression agent in the 1960s, and was used around valuable materials, such as aircraft, mainframe computers, and telecommunication switching centers, usually in total flooding systems. It was also widely used in the maritime industry to add a third level of protection should the main and emergency fire pumps become inoperable or ineffective.
It is considered good practice to avoid all unnecessary exposure to Halon 1301, and to limit exposures to concentrations of 7 percent and below to 15 minutes. Exposure to Halon 1301 in the 5 to 7 percent range produces little, if any, noticeable effect. At levels between 7 and 10 percent, mild central nervous system effects such as dizziness and tingling in the extremities have been reported. In practice, the operators of many Halon 1301 total flooding systems evacuate the space on impending agent discharge.
Due to lessons learned in the Vietnam War, the use of Halon 1301 began in the F-16 fighter aircraft to prevent vapors in the fuel tanks from becoming explosive. Upon entering areas with possible unfriendly fire, Halon 1301 is injected into the fuel tanks for one-time use. Due to environmental concerns, trifluoroiodomethane (CF3I) is being considered as an alternative.
Before the dangers of Halon 1301 as an ozone depleter were known, many industrial chillers used it as an efficient refrigerant gas.
Alternatives to Halon 1301 in fire extinguishing systems are being deployed. Many installations from which halon is removed can be protected with fire sprinklers, depending on the level of damage the equipment in the space will incur by exposure to water. In other cases, different total flooding agents can be used. The alternatives for normally occupied areas include (PFC-410 or CEA-410), C3F8 (PFC-218 or CEA-308), HCFC Blend A (NAF S-III), HFC-23 (FE 13), HFC-227ea (FM 200), IG-01 (argon), IG-55 (argonite), HFC-125, or HFC-134a. For normally unoccupied areas, the alternatives include carbon dioxide, powdered Aerosol C, CF3I, HCFC-22, HCFC-124, HFC-125, HFC-134a, gelled halocarbon/dry chemical suspension (PGA), blend of inert gas, high expansion foam systems and powdered aerosol (FS 0140), and IG-541 (Inergen). Perfluorocarbons, i.e., PFCs such as C3F8, have very long atmospheric lifetimes and very high global warming potentials. Hydrochlorofluorocarbons, i.e., HCFCs including HCFC containing NAF S-III, contain chlorine and are stratospheric ozone layer depleters, although less so than Halon 1301. Their selection for usage as Halon replacements should consider those factors, and is restricted in some countries.
- ^ "National Refrigerants MSDS". http://www.refrigerants.com/msds/r13b1.pdf. Retrieved 2009-07-17.
- ^ NFPA 12A Standard on Halon 1301 Fire Extinguishing Systems, 2004 Edition / Annex D, Hazards to Personnel , section D.2.2
- ^ Halon Substitute Protects Aircrews and the Ozone Layer
- ^ Halon 1301 Replacements
- International Chemical Safety Card 0837
- NIOSH Pocket Guide to Chemical Hazards 0634
- MSDS sheet at airliquide.com
- FAA paper on testing cylinders used to store Halon 1301 without breaking their seals (pdf)
- MSDS for bromotrifluoromethane (pdf)
- MSDS at ansul.com (pdf)
- Toxicokinetics of Inhaled Bromotrifluoromethane (Halon 1301) in Human Subjects
- Effect of CF3H and CF3Br on laminar diffusion flames in normal and microgravity
- Basic Facts about Halon
Halomethanes Monosubstituted Disubstituted Trisubstituted
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