 Operator (physics)

In physics, an operator is a function acting on the space of physical states. As a result of its application on a physical state, another physical state is obtained, very often along with some extra relevant information.
The simplest example of the utility of operators is the study of symmetry. Because of this, they are a very useful tool in classical mechanics. In quantum mechanics, on the other hand, they are an intrinsic part of the formulation of the theory.
Contents
Operators in classical mechanics
Let us consider a classical mechanics system led by a certain Hamiltonian H(q,p), function of the generalized coordinates q and its conjugate momenta. Let us consider this function to be invariant under the action of a certain group of transformations G, i.e., if . The elements of G are physical operators, which map physical states among themselves.
An easy example is given by space translations. The hamiltonian of a translationally invariant problem does not change under the transformation . Other straightforward symmetry operators are the ones implementing rotations.
If the physical system is described by a function, as in classical field theories, the translation operator is generalized in a straightforward way:
Notice that the transformation inside the parenthesis should be the inverse of the transformation done on the coordinates.
Concept of generator
If the transformation is infinitesimal, the operator action should be of the form
where I is the identity operator, is a small parameter, and A will depend on the transformation at hand, and is called a generator of the group. Again, as a simple example, we will derive the generator of the space translations on 1D functions.
As it was stated, T_{a}f(x) = f(x − a). If is infinitesimal, then we may write
This formula may be rewritten as
where D is the generator of the translation group, which happens to be just the derivative operator. Thus, it is said that the generator of translations is the derivative.
The exponential map
The whole group may be recovered, under normal circumstances, from the generators, via the exponential map. In the case of the translations the idea works like this.
The translation for a finite value of a may be obtained by repeated application of the infinitesimal translation:
with the standing for the application N times. If N is large, each of the factors may be considered to be infinitesimal:
But this limit may be rewritten as an exponential:
 T_{a}f(x) = exp( − aD)f(x).
To be convinced of the validity of this formal expression, we may expand the exponential in a power series:
The righthand side may be rewritten as
which is just the Taylor expansion of f(x − a), which was our original value for T_{a}f(x).
Operators in quantum mechanics
The mathematical description of quantum mechanics is built upon the concept of an operator.
Physical pure states in quantum mechanics are unitnorm vectors in a certain vector space (a Hilbert space). Time evolution in this vector space is given by the application of a certain operator, called the evolution operator. Since the norm of the physical state should stay fixed, the evolution operator should be unitary. Any other symmetry, mapping a physical state into another, should keep this restriction.
Any observable, i.e., any quantity which can be measured in a physical experiment, should be associated with a selfadjoint linear operator. The values which may come up as the result of the experiment are the eigenvalues of the operator. The probability of each eigenvalue is related to the projection of the physical state on the subspace related to that eigenvalue.
Table of QM operators
The operators used in quantum mechanics are collected in the table below (see for example ^{[1]}, ^{[2]}). The boldface vectors with circumflexes are not unit vectors, they are 3vector operators; all three spatial components taken together.
Operator (common name/s) Component definitions General definition SI unit Dimension Position
m [L] Momentum
J s m^{1} = N s [M] [L] [T]^{1} Potential energy
J [M] [L]^{2} [T]^{2} Energy Timeindependent:
TimeIndependent:
TimeDependent:
J [M] [L]^{2} [T]^{2} Hamiltonian J [M] [L]^{2} [T]^{2} Angular momentum operator
J s = N s m^{1} [M] [L]^{2} [T]^{1} Spin angular momentum
where
are the pauli matrices for spin½ particles.
where σ is the vector whose components are the pauli matricies.
J s = N s m^{1} [M] [L]^{2} [T]^{1} General mathematical properties of quantum operators
The mathematical properties of physical operators are a topic of great importance in itself. For further information, see C*algebra and GelfandNaimark theorem.
See also
 Position operator
 Momentum operator
 Annihilation operator
 Creation operator
 Evolution operator
 Hamiltonian operator
 Ladder operator
 Bounded linear operator
 Representation theory
References
 ^ Molecular Quantum Mechanics Parts I and II: An Introduction to QUANTUM CHEMISRTY (Volume 1), P.W. Atkins, Oxford University Press, 1977, ISBN 0198551290
 ^ Quanta: A handbook of concepts, P.W. Atkins, Oxford University Press, 1974, ISBN 0198554931
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