- Entropy in thermodynamics and information theory
There are close parallels between the mathematical expressions for the thermodynamic

entropy , usually denoted by "S", of a physical system in thestatistical thermodynamics established byLudwig Boltzmann andJ. Willard Gibbs in the 1870s; and the information-theoretic entropy, usually expressed as "H", of Claude Shannon andRalph Hartley developed in the 1940s. Shannon, although not initially aware of this similarity, commented on it upon publicizing information theory in "A Mathematical Theory of Communication ".This article explores what links there are between the two concepts, and how far they can be regarded as connected.

**Equivalence of form of the defining expressions****Discrete case**The defining expression for

entropy in the theory ofstatistical mechanics established byLudwig Boltzmann andJ. Willard Gibbs in the 1870s, is of the form::$S\; =\; -\; k\; sum\_i\; p\_i\; log\; p\_i,,$where $p\_i$ is the probability of the microstate "i" taken from an equilibrium ensemble.The defining expression for entropy in the theory of information established by

Claude E. Shannon in 1948 is of the form::$H\; =\; -\; sum\_i\; p\_i\; log\; p\_i,,$where $p\_i$ is the probability of the message $m\_i$ taken from the message space "M".Mathematically "H" may also be seen as an

average information , taken over the message space, because when a certain message occurs with probability "p"_{"i"}, the information −log("p"_{"i"}) will be obtained.If all the microstates are equiprobable (a

microcanonical ensemble ), the statistical thermodynamic entropy reduces to the form on Boltzmann's tombstone,:$S\; =\; k\; log\; W\; ,$where "W" is the number of microstates.If all the messages are equiprobable, the information entropy reduces to the

Hartley entropy :$H\; =\; log\; |M|,$where $|M|$ is thecardinality of the message space "M".The logarithm in the thermodynamic definition is the

natural logarithm . It can be shown that the Gibbs entropy formula, with the natural logarithm, reproduces all of the properties of the macroscopicclassical thermodynamics ofClausius . (See article:Entropy (statistical views) ).The

logarithm can also be taken to the natural base in the case of information entropy. This is equivalent to choosing to measure information in nats instead of the usualbits . In practice, information entropy is almost always calculated using base 2 logarithms, but this distinction amounts to nothing other than a change in units. One nat is about 1.44 bits.The presence of

Boltzmann's constant "k" in the thermodynamic definitions is a historical accident, reflecting the conventional units of temperature. It is there to make sure that the statistical definition of thermodynamic entropy matches the classical entropy of Clausius, thermodynamically conjugate totemperature . For a simple compressible system that can only perform volume work, thefirst law of thermodynamics becomes:$dE\; =\; -p\; dV\; +\; T\; dS\; ,$But one can equally well write this equation in terms of what physicists and chemists sometimes call the 'reduced' or dimensionless entropy, σ = "S"/"k", so that:$dE\; =\; -p\; dV\; +\; kT\; dsigma\; ,$Just as "S" is conjugate to "T", so σ is conjugate to "kT" (the energy that is characteristic of "T" on a molecular scale).**Continuous case**The most obvious extension of the Shannon entropy is the

differential entropy ,:$H\; [f]\; =\; -int\_\{-infty\}^\{infty\}\; f(x)\; log\; [\; f(x)]\; ,\; dx,quad$As long as "f"("x") is a probability density function, p. d. f., "H" repesents the

average information (entropy ,disorder , diversity etcetera) of "f"("x"). For any uniform p. d. f. "f"("x"), the exponential of "H" is the volume covered by "f"("x") (in analogy to thecardinality in the discrete case). The volume covered by a n-dimensionalmultivariate Gaussian distribution with moment matrix M is proportional to the volume of the ellipsoid of concentration and is equal to "$sqrt\{(2\; pi\; e)^\{n\}\; det(M)\}$". The volume is always positive.Average information may be maximized usingGaussian adaptation - one of theevolutionary algorithms - keeping themean fitness - i. e. the probability of becoming a parent to new individuals in the population - constant (and without the need for any knowledge aboutaverage information as a criterion function). This is illustrated by the figure below, showing Gaussian adaptation climbing a mountain crest in a phenotypic landscape. The lines in the figure are part of a contour line enclosing a region of acceptability in the landscape. At the start the cluster of red points represents a very homogeneous population with small variances in the phenotypes. Evidently, even small environmental changes in the landscape, may cause the process to become extinct.After a sufficiently large number of generations, the increase in

average information may result in the green cluster. Actually, themean fitness is the same for both red and green cluster (about 65%). The effect of this adaptation is not very salient in a 2-dimensional case, but in a high-dimensional case, the efficiency of the search process may be increased by many orders of magnitude.Besides, a Gaussian distribution has the highest

average information as compared to other distributions having the same second order moment matrix (Middleton 1960).But it turns out that this is "not" in general a good measure of uncertainty or information. For example, the differential entropy can be negative; also it is not invariant under continuous coordinate transformations.

Jaynes showed in fact in [*http://bayes.wustl.edu/etj/articles/brandeis.pdf*] (sect. 4b) that the expression above is not the correct limit of the expression for a finite set of probabilities.The correct expression, appropriate for the continuous case, is the

**relative entropy**of a distribution, defined as theKullback-Leibler divergence from the distribution to a reference measure "m"("x"),:$D\_\{mathrm\{KL(f(x)|m(x))\; =\; int\; f(x)logfrac\{f(x)\}\{m(x)\},dx$(or sometimes the negative of this).The relative entropy carries over directly from discrete to continuous distributions, and is invariant under coordinate reparamatrisations. For an application of relative entropy in a quantum information theory setting, see eg [

*http://arxiv.org/abs/math-ph/0007010/*] .**Theoretical relationship**Despite all that, there is an important difference between the two quantities. The information entropy "H" can be calculated for "any" probability distribution (if the "message" is taken to be that the event "i" which had probability "p

_{i}" occurred, out of the space of the events possible). But the thermodynamic entropy "S" refers to thermodynamic probabilities "p_{i}" specifically.Furthermore, the thermodynamic entropy "S" is dominated by different arrangements of the system, and in particular its energy, that are possible on a molecular scale. In comparison, information entropy of any macroscopic event is so small as to be completely irrelevant.

However, a connection can be made between the two, if the probabilities in question are the thermodynamic probabilities "p

_{i}": the (reduced) Gibbs entropy σ can then be seen as simply the amount of Shannon information needed to define the detailed microscopic state of the system, given its macroscopic description. Or, in the words ofG. N. Lewis writing about chemical entropy in 1930, "Gain in entropy always means loss of information, and nothing more". To be more concrete, in the discrete case using base two logarithms, the reduced Gibbs entropy is equal to the minimum number of yes/no questions that need to be answered in order to fully specify the microstate, given that we know the macrostate.Furthermore, the prescription to find the equilibrium distributions of statistical mechanics, such as the Boltzmann distribution, by maximising the Gibbs entropy subject to appropriate constraints (the

Gibbs algorithm ), can now be seen as something not unique to thermodynamics, but as a principle of general relevance in all sorts of statistical inference, if it desired to find a maximally uninformative probability distribution, subject to certain constraints on the behaviour of its averages. (These perspectives are explored further in the article "Maximum entropy thermodynamics ").**Information is physical****zilard's engine**A neat physical

thought-experiment demonstrating how just the possession of information might in principle have thermodynamic consequences was established in 1929 by Szilard, in a refinement of the famousMaxwell's demon scenario.Consider Maxwell's set-up, but with only a single gas particle in a box. If the supernatural demon knows which half of the box the particle is in (equivalent to a single bit of information), it can close a shutter between the two halves of the box, close a piston unopposed into the empty half of the box, and then extract $k\_B\; T\; ln\; 2$ joules of useful work if the shutter is opened again. The particle can then be left to isothermally expand back to its original equilibrium occupied volume. In just the right circumstances therefore, the possession of a single bit of Shannon information (a single bit of

negentropy in Brillouin's term) really does correspond to a reduction in physical entropy, which theoretically can indeed be parlayed into useful physical work.**Landauer's principle**In fact one can generalise: any information that has a physical representation must somehow be embedded in the statistical mechanical degrees of freedom of a physical system.

Thus,

Rolf Landauer argued in 1961, if one were to imagine starting with those degrees of freedom in a thermalised state, there would be a real reduction in thermodynamic entropy if they were then re-set to a known state. This can only be achieved under information-preserving microscopically deterministic dynamics if the uncertainty is somehow dumped somewhere else — ie if the entropy of the environment (or the non information-bearing degrees of freedom) is increased by at least an equivalent amount, as required by the Second Law, by gaining an appropriate quantity of heat: specifically "kT" ln 2 of heat for every 1 bit of randomness erased.On the other hand, Landauer argued, there is no thermodynamic objection to a logically reversible operation potentially being achieved in a physically reversible way in the system. It is only logically irreversible operations — for example, the erasing of a bit to a known state, or the merging of two computation paths — which must be accompanied by a corresponding entropy increase.

Applied to the Maxwell's demon/Szilard engine scenario, this suggests that it might be possible to "read" the state of the particle into a computing apparatus with no entropy cost; but "only" if the apparatus has already been SET into a known state, rather than being in a thermalised state of uncertainty. To SET (or RESET) the apparatus into this state will cost all the entropy that can be saved by knowing the state of Szilard's particle.

**Negentropy**Shannon entropy has been related by physicist

Léon Brillouin to a concept sometimes callednegentropy . In his 1962 book "Science and Information Theory", Brillouin described the Negentropy Principle of Information or NPI, the gist of which is that acquiring information about a system’s microstates is associated with a decrease in entropy (work is needed to extract information, erasure leads to increase in thermodynamic entropy). [*http://www.talkorigins.org/faqs/information/shannon.html#Entropy Classical Information Theory (Shannon)*] – Talk Origins Archive ] There is no violation of the second law of thermodynamics, according to Brillouin, since a reduction in any local system’s thermodynamic entropy results in an increase in thermodynamic entropy elsewhere. Negentropy is a controversial concept as it yields Carnot efficiency higher than one.Fact|date=July 2008**Black holes**Stephen Hawking often speaks of the thermodynamic entropy ofblack hole s in terms of their information content. Do black holes destroy information? See "Black hole thermodynamics " and "Black hole information paradox ".**Quantum theory**Hirschman showed in 1957, however, that

Heisenberg's uncertainty principle can be expressed as a particular lower bound on the sum of the entropies of the "observable" probability distributions of a particle's position and momentum, when they are expressed inPlanck units . (One could speak of the "joint entropy" of these distributions by considering them independent, but since they are not jointly observable, they cannot be considered as a joint distribution.)It is well known that a Shannon based definition of information entropy leads in the classical case to the Boltzmann entropy. It is tempting to regard the Von Neumann entropy as the corresponding quantum mechanical definition. But the latter is problematic from quantum information point of view. Consequently Stotland, Pomeransky, Bachmat and Cohen have introduced a new definition of entropy that reflects the inherent uncertainty of quantum mechanical states. This definition allows to distinguish between the minimum uncertainty entropy of pure states, and the excess statistical entropy of mixtures.

* [*http://arxiv.org/abs/quant-ph/0401021 The information entropy of quantum mechanical states*] , Europhysics Letters 67, 700 (2004).**The fluctuation theorem**The

fluctuation theorem provides a mathematical justification of thesecond law of thermodynamics under these principles, and precisely defines the limitations of the applicability of that law to the microscopic realm of individual particle movements.**Topics of recent research****Is information quantized?**In 1995,

Tim Palmer signalled two unwritten assumptions about Shannon's definition of information that may make it inapplicable as such toquantum mechanics :* The supposition that there is such a thing as an observable state (for instance the upper face of a die or a coin) "before" the observation begins

* The fact that knowing this state does not depend on the order in which observations are made (commutativity)

The article "Conceptual inadequacy of the Shannon information in quantum measurement" [

*http://scitation.aip.org/getabs/servlet/GetabsServlet?prog=normal&id=PLRAAN000063000002022113000001&idtype=cvips&gifs=yes*] , published in 2001 byAnton Zeilinger [*http://www.quantum.univie.ac.at/zeilinger/*] andCaslav Brukner , synthesized and developed these remarks. The so-calledZeilinger's principle suggests that the quantization observed in QM could be bound to "information" quantization (one cannot observe less than one bit, and what is not observed is by definition "random").But these claims remain highly controversial. For a detailed discussion of the applicability of the Shannon information in quantum mechanics and an argument that Zeilinger's principle cannot explain quantization, see Timpson [

*http://www.philosophy.leeds.ac.uk/Staff/CT/Index.htm*] 2003 [*http://arxiv.org/abs/quant-ph/0112178*] and also Hall 2000 [*http://arxiv.org/abs/quant-ph/0007116*] and Mana 2004 [*http://arxiv.org/abs/quant-ph/0302049*] , who shows that Brukner and Zeilinger change, in the middle of the calculation in their article, the numerical values of the probabilities needed to compute the Shannon entropy, so that the calculation makes no sense.For a tutorial on quantum information see [

*http://members.aol.com/jmtsgibbs/infothry.htm*] .**ee also*** Thermodynamic entropy

*Information entropy

*Thermodynamics

*Statistical mechanics

*Information theory

*Physical information

*Fluctuation theorem

*Black hole entropy

*Black hole information paradox **External links*** [

*http://www.entropysimple.com/content.htm Entropy is Simple...If You Avoid the Briar Patches*] . Dismissive of direct link between information-theoretic and thermodynamic entropy.**References*** C. H. Bennett, "Logical reversibility of computation," IBM Journal of Research and Development, vol. 17, no. 6, pp. 525-532, 1973.

* Leon Brillouin, "Science and Information Theory", Mineola, N.Y.: Dover, [1956, 1962] 2004. ISBN 0-486-43918-6

* Michael P. Frank, [*http://www.cise.ufl.edu/research/revcomp/physlim/plpaper.html "Physical Limits of Computing"*] , "Computing in Science and Engineering",**4**(3):16-25, May/June 2002.

* Andreas Greven, Gerhard Keller, and Gerald Warnecke, editors. "Entropy", Princeton University Press, 2003. ISBN 0-691-11338-6. (A highly technical collection of writings giving an overview of the concept of entropy as it appears in various disciplines.)

* I. Hirschman, "A Note on Entropy", American Journal of Mathematics, 1957.

* R. Landauer, "Information is Physical" Proc. Workshop on Physics and Computation PhysComp'92 (IEEE Comp. Sci.Press, Los Alamitos, 1993) pp. 1-4.

* R. Landauer, [*http://domino.research.ibm.com/tchjr/journalindex.nsf/c469af92ea9eceac85256bd50048567c/8a9d4b4e96887b8385256bfa0067fba2?OpenDocument "Irreversibility and Heat Generation in the Computing Process"*] IBM J. Res. Develop. Vol. 5, No. 3, 1961

* H. S. Leff and A. F. Rex, Editors, "Maxwell's Demon: Entropy, Information, Computing", Princeton University Press, Princeton, NJ (1990). ISBN 0-691-08727-X

* Middleton, D. An Introduction to Statistical Communication Theory. McGraw-Hill, 1960.

* Claude E. Shannon. "A Mathematical Theory of Communication ". Bell System Technical Journal, July/October 1948.

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