- Germanium tetrachloride
Germanium tetrachloride Identifiers CAS number PubChem ChemSpider RTECS number LY5220000 Jmol-3D images Image 1 Properties Molecular formula GeCl4 Molar mass 214.40 g/mol Appearance colourless liquid Density 1.879 g/cm3 (20 °C)
1.844 g/cm3 (30 °C) 
-49.5 °C, 224 K, -57 °F
86.5 °C, 360 K, 188 °F
Solubility in water decomp. Solubility soluble in ether, benzene, chloroform, CCl4
insoluble in HCl, H2SO4
Refractive index (nD) 1.464 Structure Molecular shape tetrahedral Hazards MSDS "External MSDS" EU Index Not listed Main hazards Reacts slowly with water to form HCl and GeO2, corrosive, lachrymator NFPA 704 Flash point Not flammable Related compounds Other anions Germanium tetrafluoride
Other cations Carbon tetrachloride
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Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)
Germanium tetrachloride is a colourless liquid used as an intermediate in the production of purified germanium metal. In recent years, GeCl4 usage has increased substantially due to its use as a reagent for fiber optic production.
Most commercial production of germanium is from treating flue-dusts of zinc- and copper-ore smelters, although a significant source is also found in the ash from the combustion of certain types of coal called vitrain. Germanium tetrachloride is an intermediate for the purification of germanium metal or its oxide, GeO2.
Germanium tetrachloride can be generated directly from GeO2 by dissolution of the oxide in concentrated hydrchloric acid. The resulting mixture is fractionally distilled to purify and separate the germanium tetrachloride from other products and impurities. The GeCl4 can be rehydrolyzed with deionized water to produce pure GeO2, which is then reduced under hydrogen to produce germanium metal.
Production of GeO2, however, is dependent on the oxidized form of germanium extracted from the ore. Copper-lead-sulfide and zinc-sulfide ores will produce GeS2, which is subsequently oxidized to GeO2 with an oxidizer such as sodium chlorate. Zinc-ores are roasted and sintered and can produce the GeO2 directly. The oxide is then processed as discussed above.
Germanium tetrachloride is used almost exclusively as an intermediate for several optical processes. GeCl4 can be directly hydrolyzed to GeO2, an oxide glass with several unique properties and applications, described below:
Most notable of GeO2 is its high index of refraction and low optical dispersion, used for wide camera lens, microscopy, and for the core of fiber-optic lines. See Optical fiber for specifics on the manufacturing process. Overall, silicon tetrachloride, SiCl4 and germanium tetrachloride, GeCl4 are introduced with oxygen into a hollow glass preform, which is carefully heated to allow for oxidation of the reagents to their respective oxides and formation of a glass mixture. The GeO2 has a high index of refraction, so by varying the flowrate of germanium tetrachloride the overall index of refraction of the optical fiber can be specifically controlled. The GeO2 is about 4% by weight of the glass.
Germanium and its glass oxide, GeO2 are transparent to the infrared spectrum. The glass can be manufactured into IR windows and lenses, used for night-vision technology in the military and luxury vehicles. GeO2 is preferred over other IR transparent glasses because it is mechanically strong and therefore preferred for rugged military usage.
As of the year 2000, about 15% of United States consumption of germanium is used for infrared optics technology and 50% for fiber-optics. Over the past 20 years, infrared use has consistently decreased; fiber optic demand, however, is slowly increasing. There is discussion on the over-production of fiber-optic networks and that 30-50% of current lines are unused dark fiber, suggesting a future reduction in demand. Worldwide, demand is increasing dramatically as countries such as China are expanding fiber-optic based telecommunication throughout the country.
- ^ Pradyot Patnaik. Handbook of Inorganic Chemicals. McGraw-Hill, 2002, ISBN 0070494398
- ^ a b c d e f "Germanium" Mineral Commodity Profile, U.S. Geological Survey, 2005.
- ^ a b c d "The Elements" C.R. Hammond, David R. Lide, ed. CRC Handbook of Chemistry and Physics, Edition 85 (CRC Press, Boca Raton, FL) (2004)
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