Otto Wallach


Otto Wallach
Otto Wallach

Born 27 March 1847
Königsberg, Prussia
Died 26 February 1931( 1931-02-26) (aged 83)
Göttingen, Germany
Nationality Prussia / German Empire
Fields Organic chemistry
Institutions University of Göttingen,
University of Bonn
Alma mater University of Göttingen
Doctoral advisor August Wilhelm von Hofmann,
Friedrich Wöhler,
Friedrich Kekulé
Doctoral students Walter Haworth
Known for Isoprene rule
Notable awards Nobel Prize for Chemistry (1910)

Otto Wallach (27 March 1847 - 26 February 1931) was a German chemist and recipient of the 1910 Nobel prize in Chemistry for his work on alicyclic compounds.[1][2]

Contents

Biography

Wallach was born in Königsberg, the son of a Prussian official. His father descended from a Jewish family that had converted to Lutheranism. His mother was an ethnic German of Protestant religion. Wallach's father was transferred to Stettin (Szczecin) and later to Potsdam. Otto Wallach went to school, a Gymnasium, in Potsdam, where he learned about literature and the history of art, two subjects he was interested his whole life. At this time he also started private chemical experiments at the house of his parents.

In 1867 he started studying chemistry at the University of Göttingen, where at this time Friedrich Wöhler was head of organic chemistry. After one semester at the University of Berlin with August Wilhelm von Hofmann, Wallach received his Doctoral degree from the University of Göttingen in 1869, and worked as a Professor in the University of Bonn (1870–89) and the University of Göttingen (1889–1915). Wallach died at Göttingen.

Major works

During his work with Friedrich Kekulé in Bonn he started a systematic analysis of the terpenes present in essential oils. Up to this time only a few had been isolated in pure form, and structural information was sparse. Melting point comparison and the measurement of mixtures was one of the methods to confirm identical substances. For this method the mostly liquid terpenes had to be transformed into crystalline compounds. With stepwise derivatisation, especially additions to the double bond present in some of the terpenes, he achieved the goal of obtaining crystalline compounds. The investigation of the rearrangement reactions of cyclic unsaturated terpenes made it possible to obtain the structure of an unknown terpene by following the rearangments to a known structure of a terpene. With these principal methods he opened the path to systematic research on terpenes.

AlphaPinene.png

He was responsible for naming terpene and pinene, and for undertaking the first systematic study of pinene^ .

He wrote a book about the chemistry of terpenes, "Terpene und Campher" (1909).

Otto Wallach is known for Wallach's rule, Wallach degradation, the Leuckart-Wallach reaction and the Wallach rearrangement.

References

  1. ^ Leopold Ruzicka (1932). "Third Pedler lecture. The life and work of Otto Wallach". J. Chem. Soc.: 1582. doi:10.1039/JR9320001582. 
  2. ^ Christmann, M. (2010), Otto Wallach: Founder of Terpene Chemistry and Nobel Laureate 1910. Angewandte Chemie International Edition, 49: 9580–9586. doi:10.1002/anie.201003155

External links



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