Negative hyperconjugation
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Hyperconjugation — In organic chemistry, hyperconjugation is the interaction of the electrons in a sigma bond (usually C–H or C–C) with an adjacent empty (or partially filled) non bonding p orbital or antibonding π orbital or filled π orbital, to give an extended… … Wikipedia
Covalent radius of fluorine — The covalent radius of fluorine is a measure of the size of a fluorine atom; it is approximated at about 60 picometres. Since fluorine is a relatively small atom with a large electronegativity, its covalent radius is difficult to evaluate. The… … Wikipedia
Chemical bond — A chemical bond is an attraction between atoms that allows the formation of chemical substances that contain two or more atoms. The bond is caused by the electromagnetic force attraction between opposite charges, either between electrons and… … Wikipedia
Resonance (chemistry) — For other uses, see Resonance (disambiguation). Two of the contributing structures of nitrogen dioxide In chemistry, resonance or mesomerism [1] is a way of describing delocalized electrons within certain molecules or … Wikipedia
Chemical polarity — Polar molecule and Nonpolar redirect here. For other uses see Polar (disambiguation). A water molecule, a commonly used example of polarity. The two charges are present with a negative charge in the middle (red shade), and a positive charge at… … Wikipedia
Hyperkonjugation — Unter Hyperkonjugation versteht man in der organischen Chemie eine elektronische Wechselwirkung zwischen einem vollständig besetzten Orbital einer σ Bindung (meist einer C H oder C C Bindung) und einem benachbarten unbesetzten oder einfach… … Deutsch Wikipedia
Intermolecular force — Intermolecular forces (forces between two molecules) are weak compared to the intramolecular forces (forces keeping a molecule together). For example, the covalent bond present within HCl molecules is much stronger than the forces present between … Wikipedia
Metallic bond — Metallic bonding is the electrostatic attractive forces between the delocalized electrons, called conduction electrons, gathered in an electron sea , and the positively charged metal ions. Understood as the sharing of free electrons among a… … Wikipedia
Van der Waals force — In physical chemistry, the van der Waals force (or van der Waals interaction), named after Dutch scientist Johannes Diderik van der Waals, is the sum of the attractive or repulsive forces between molecules (or between parts of the same molecule)… … Wikipedia
Delocalized electron — Benzene, with the delocalization of the electrons indicated by the circle. In chemistry, delocalized electrons are electrons in a molecule, ion or solid metal that are not associated with a single atom or one covalent bond. [ … Wikipedia
A schematic representation of negative hyperconjugation. In real systems, several of the hydrogens are replaced with other functional groups.
