- An Experimental Enquiry Concerning the Source of the Heat which is Excited by Friction
Rumford was an opponent of the
caloric theoryof heat which held that heat was a fluid that could be neither created nor destroyed. He had further developed the view that all gases and liquids were absolute non-conductors of heat. His views were out of step with the accepted science of the time and the latter theory had particularly been attacked by John Daltonref|JD and John Leslieref|JL.
Rumford was heavily influenced by the theological
argument from designref|R1 and it is likely that he wished to grant water a privileged and providential status in the regulation of human liferef|C1.
Though Rumford was to come to associate heat with motion, there is no evidence that he was committed to the
kinetic theoryor the principle of " vis viva".
Rumford had observed the
frictional heat generated by boring cannonat the arsenalin Munich. Rumford immersed a cannon barrel in waterand arranged for a specially blunted boring tool. He showed that the water could be boiled within roughly two and a half hours and that the supply of frictional heat was seemingly inexhaustible. Rumford confirmed that no physical change had taken place in the material of the cannon by comparing the specific heats of the material machined away and that remaining were the same.
Rumford argued that the seemingly indefinite generation of heat was incompatible with the caloric theory. He contended that the only thing communicated to the barrel was motion.
Rumford made no attempt to further quantify the heat generated or to measure the
mechanical equivalent of heat.
Most established scientists, such as William Henryref|WH and
Thomas Thomsonref|TT, believed that there was enough uncertainty in the caloric theory to allow its adaptation to account for the new results. It had certainly proved robust and adaptable up to that time.
Jöns Jakob Berzeliusand Antoine César Becquerelobserved that electricitycould be indefinitely generated by friction. No educated scientist of the time was willing to hold that electricity was not a fluid.
Ultimately, Rumford's claim of the "inexhaustible" supply of heat was a reckless
extrapolationfrom the study. Charles Haldatmade some penetrating criticisms of the reproducibilityof Rumford's resultsref|CH and it is possible to see the whole experiment as somewhat tendentiousref|C2.
However, the experiment inspired the work of
James Prescott Joulein the 1840s. Joule's more exact measurements were pivotal in establishing the kinetic theory at the expense of caloric.
#Cardwell (1971) "p."99
#cite book | author=Leslie, J. | title=An Experimental Enquiry into the Nature and Propagation of Heat | publisher=London | year=1804 | id=
#Rumford (1804) "An enquiry concerning the nature of heat and the mode of its communication" "Philosophical Transactions of the Royal Society" "p."77
#Cardwell (1971) "pp"99-100
#Henry, W. (1802) "A review of some experiments which have been supposed to disprove the materiality of heat", "
Manchester Memoirs" "v", "p."603
#Thomson, T. "Caloric", Supplement on Chemistry, "
Encyclopædia Britannica", 3rd ed.
#Haldat, C.N.A (1810) "Inquiries concerning the heat produced by friction", "Journal de Physique" lxv, "p."213
#Cardwell (1971) "p."102
*cite book | author=Cardwell, D.S.L. | title=From Watt to Clausius: The Rise of Thermodynamics in the Early Industrial Age | location=Heinemann | publisher=London | year=1971 | id=ISBN 0-435-54150-1
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