allylic

allylic
adjective Date: 1857 involving or characteristic of an allyl radical

New Collegiate Dictionary. 2001.

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  • allylic — /euh lil ik/, adj. of, pertaining to, or characteristic of the allyl group. [1855 60; ALLYL + IC] * * * …   Universalium

  • allylic — adjective əˈlɪlɪk Containing an allyl group, an alkene hydrocarbon group with the formula HC=CH CH …   Wiktionary

  • allylic — al·lyl·ic …   English syllables

  • allylic — adjective of or pertaining to the allyl radical • Pertains to noun: ↑allyl group • Derivationally related forms: ↑allyl • Topics: ↑chemistry, ↑chemical science …   Useful english dictionary

  • Allylic strain — or 1,3 allylic strain in organic chemistry and its associated strain energy results from an unfavorable molecular conformation for the allyl group. The simplest representative of the allyls, propene, in its ground state has the methyl C H bond… …   Wikipedia

  • Allylic rearrangement — An allylic rearrangement or allylic shift is an organic reaction in which the double bond in an allyl chemical compound shifts to the next carbon atom. It is encountered in nucleophilic substitution.In reaction conditions that favor a SN1… …   Wikipedia

  • allylic rearrangement — alilinis persigrupavimas statusas T sritis chemija apibrėžtis Dvigubojo ryšio vietos pakeitimas alilo grupės fragmente. atitikmenys: angl. allylic rearrangement rus. аллильная перегруппировка …   Chemijos terminų aiškinamasis žodynas

  • allylic rearrangement — noun : the migration of an ion or radical from one end of a 3 carbon allyl sequence to the other with concurrent shifting of the position of the double bond (as CH2=CHCHRX → XCH2CH=CHR) …   Useful english dictionary

  • Trost asymmetric allylic alkylation — The Trost asymmetric allylic alkylation or Trost AAA or allylic asymmetric substitution is an organic reaction used in asymmetric synthesis. [Trost, B. M.; Fullerton, T. J. New synthetic reactions. Allylic alkylation. J. Am. Chem. Soc. 1973, 95 …   Wikipedia

  • Desulfonylation reactions — are chemical reactions leading to the removal of a sulfonyl group from organic compounds. As the sulfonyl functional group is electron withdrawing, methods for cleaving the sulfur carbon bonds of sulfones are typically reductive in nature.… …   Wikipedia

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