Antimony(III) acetate

Antimony(III) acetate
IUPAC name Antimony(III) acetate
Other names Antimony triacetate Acetic acid, antimony(3+) salt Octan antimonity<
Identifiers
CAS number	6923-52-0
ChemSpider	21839 Y
Jmol-3D images	Image 1 Image 2
SMILES CC(=O)[O-].CC(=O)[O-].CC(=O)[O-].[SbH3+3] CC(=O)[O-].CC(=O)[O-].CC(=O)[O-].[Sb+3]
InChI InChI=1S/3C2H4O2.Sb/c3*1-2(3)4;/h3*1H3,(H,3,4);/q;;;+3/p-3 Y Key: JVLRYPRBKSMEBF-UHFFFAOYSA-K Y InChI=1/3C2H4O2.Sb.3H/c3*1-2(3)4;;;;/h3*1H3,(H,3,4);;;;/q;;;+3;;;/p-3/r3C2H4O2.H3Sb/c3*1-2(3)4;/h3*1H3,(H,3,4);1H3/q;;;+3/p-3 Key: NSMVVPJZMRQLMR-ZHOQVWKLAW InChI=1/3C2H4O2.Sb/c3*1-2(3)4;/h3*1H3,(H,3,4);/q;;;+3/p-3 Key: JVLRYPRBKSMEBF-DFZHHIFOAU
Properties
Molecular formula	C6H9O6Sb
Molar mass	298.89 g mol−1
Appearance	White powder
Density	1.22 g/cm³ (20 °C)
Melting point	127 °C, 400 K, 261 °F
Hazards
NFPA 704	0 1 0
LD50	4480 mg/kg (rat)
Y (verify) (what is: Y/N?) Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)
Infobox references

Antimony(III) acetate is the antimony salt of acetic acid with the chemical formula of Sb(CH₃COO)₃. It has the appearance of a white powder and is used as a catalyst in the production of synthetic fibers. It can be prepared by the reaction of antimony(III) oxide with acetic acid:

Sb₂O₃ + 6 HC₂H₃O₂ → 2 Sb(C₂H₃O₂)₃ + 3H₂O

The crystal structure of antimony(III) acetate has been determined by X-ray crystallography. It consists of discrete Sb(OAc)₃ monomers with monodentate acetate ligands. The monomers are linked together into chains by weaker C=O···Sb intermolecular interactions.^[1]

References

1. ^ Hall, M.; Sowerby, D. B. (1980). "Antimony(III) acetate and thioacetate: spectra and crystal structures". J. Chem. Soc., Dalton Trans. (8): 1292–1296. doi:10.1039/DT9800001292.